The four-time world champion tried to sneak around Piastri at the first corner, however the Red Bull clipped the McLaren forcing them both to spin and tumble down the order.
Ferrari back in F1 title fight after Max Verstappen and Oscar Piastri incident
Following a P19 start due to a grid penalty Leclerc found himself at the bottom of the pack, but managed to storm his way to P6.
McLaren and Ferrari remain locked in an intense battle for the constructors' crown, with the first lap crash bringing the Scuderia back into the title fight.
Meanwhile, Verstappen was not the only Red Bull to suffer on the opening lap, where Sergio Perez span and came to a halt in the final sector.
Lando Norris retained his lead despite the first lap chaos, and Carlos Sainz was promoted to P2, whilst the Alpine of Pierre Gasly found his way up into a podium position and into P3.